This invention discloses a
coordination polymer-coated catalytic material derived from twisted
polypyrrole nanotubes, its preparation method, and its applications. First, using a chiral surfactant as a template, a
helical polymer structure is formed by inducing
polymer monomers to act as the core. Then, a
transition metal source is introduced to further assemble a
helical support. Next, an organic ligand is used for coordination
coating to form a shell. Finally, after
pyrolysis under an
inert gas, a dense twisted
carbon layer is formed at the core-shell interface, yielding the
coordination polymer-coated catalytic material derived from twisted
polypyrrole nanotubes. The introduction of the
helical core in this catalytic material not only helps form a twisted carbon interface but also helps induce a uniform distribution of
transition metal active sites. The preparation method of this invention is convenient, and the obtained catalytic material exhibits good
oxygen reduction / evolution
bifunctional catalytic activity, stability, and applicability to flexible
zinc-air batteries.