The invention discloses a non-burned glaze-like coating as well as a preparation method and an application thereof. The coating is prepared from components in parts by weight as follows: 28-35 parts of organosilicone modified acrylic resin, 26-32 parts of polyurethane organosilicone modified acrylic resin, 3-5 parts of a silane coupling agent, 3-30 parts of a nano pigment, 6-10 parts of a functional aid and 10-20 parts of a mixed solution. The non-burned glaze-like coating can form a glaze-like effect and guarantee ultrahigh strength, high scratch resistance and high wear resistance of the coating and has excellent outdoor weather resistance. The non-burned glaze-like coating can be directly matched with epoxy antirust primer, electrophoretic primer, powder coatings, acrylic paint and other antirust paint or various primers to form complete coating and can be applied to outdoor infrastructure such as poles on two sides of urban roads, guardrails, street lamp poles, traffic signal lights, power distribution cabinets, dustbins and the like with high hardness and weather resistance requirements and outdoor artware such as flowerpots, flower stands, chairs and stools, animal statues and the like.