In a method for transmitting radio link protocol frames in a mobile radio communication system, if an error occurs on a radio section when user data frames of a radio link protocol (RLP) having respective different series numbers are transferred from a transmitting station to a receiving station, at least one missed user data frame is caused at the receiving station. At this time, the receiving station transmits, repeatedly by first times, a negative acknowledgement (NAK) control frame of the RLP for at least one missed user data frame, to the transmitting station. The transmitting station sends, by second times different from the first times, at least one missed user data frame in response to the received NAK control frame, to the receiving station. Particularly, series numbers of respective missed user data frames are sent through one NAK control frame to the transmitting station, at equal time when a timer for an NAK is expired, to accordingly result in reducing the number of the total NAK control frames and increasing a throughput per unit time.