The invention discloses a co-production preparation method of 2-chloro-3,3,3-trifluoropropene and 2,3-dichloro-1,1-difluoro propylene, comprising the following steps: activating and dewatering a Cr2O3-Al2O3 catalyst; then fluoridising; performing inerting on a 1,1,2,3- tetrachloro propylene mixed gas diluted by inert gas; causing hydrogen fluoride and 1,1,2,3-tetrachloro propylene mixed gas to react under the action of fluoridised and inerted Cr2O3-Al2O3 catalyst to obtain 2-chloro-3,3,3-trifluoropropene and 2,3- dichloro-1,1-difluoro propylene after an effluent is introduced in a rectifying tower; and obtaining the product after deacidification and distillation processing. With the method, the 2-chloro-3,3,3-trifluoropropene and the 2,3-dichloro-1,1-difluoro propylene can be simultaneously obtained. After the reaction, the conversion rate of the 1,1,2,3-tetrachloro propylene is 99%.