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48results about How to "Regular particle size distribution" patented technology

Preparation method for lithium ion secondary battery positive pole active substance lithium iron phosphate

The invention relates to a preparation method of lithium iron phosphate, an active substance applied in the anode of lithium-ion secondary batteries. The method comprises a mixture that contains lithium compound, iron compound, phosphorus compound and carbon source additive is sintered and cooled to get a sintering product; wherein, the iron compound is ferric iron compound; the sintering method is carried out in inert atmosphere or reducing atmosphere; the mixture is sintered at a first constant sintering temperature, and then the sintering product is acquired; the sintering product acquired from sintering at the first sintering temperature is cooled to room temperature and ground; the mixture is sintered at a second constant sintering temperature, and is cooled to room temperature in inert atmosphere or reducing atmosphere; the second sintering temperature is at least 100 DEG C higher than the first sintering temperature. The lithium iron phosphate acquired by the method of the invention has relatively high specific discharge capacity and specific volumetric capacity, and the produced batteries have small size, high capacity and good discharge performance at high current, and the invention can combine the advantages of lithium iron phosphate prepared by taking ferrous iron and ferric iron as iron sources respectively, thus the performance can be remarkably improved.
Owner:BYD CO LTD

A kind of preparation method and use of titanium cobalt spinel

A preparation method and application of titanium-cobalt spinel belongs to preparation methods and applications of transition-metal spinel, and specifically is a preparation method for a titanium-cobalt spinel (Co2TiO4) octahedral-nanostructure material and an application of the titanium-cobalt spinel (Co2TiO4) octahedral-nanostructure material to a negative electrode material of a lithium ion battery. A mild liquid phase synthesis technique is utilized to prepare a cobalt titanate nanostructure, and parameters in a reaction process are adjusted and controlled, so that the titanium-cobalt spinel octahedral-nanostructure material is compounded conveniently in low cost and is applied as the negative electrode material of the lithium ion battery. The preparation method comprises the steps of: respectively preparing solutions by utilizing a titanium source and a cobalt source, mixing the prepared solutions according to a molar ratio of (1-5) : 1, stirring the mixed solution uniformly, and putting the uniformly stirred solution in a closed pressure-resistant vessel to react for 8-40 hours at 100-250 DEG C, wherein an alkali additive is added to the titanium-source preparation solution, and a saccharide additive and an amine additive are added to the cobalt-source preparation solution. According to the preparation method, the raw materials are easy to obtain, a synthesis method is simple, and the controllability of operation steps is high; the obtained titanium-cobalt spinel has high purity and uniform particle size, and expanded production is easy. If the titanium-cobalt spinel octahedral-nanostructure material is taken as the negative electrode material of the lithium ion battery, the electrochemical performance is excellent.
Owner:CHINA UNIV OF MINING & TECH
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