The invention relates to application of a disulfide compound in crop protection. The invention discloses application of the disulfide compound shown by a structural formula (I) in serving as a plant growth regulator, a soil disinfectant or a pesticide synergist, wherein R1 and R2 independently represent C1-C6 alkyl, C3-C6 cycloalkyl, C2-C6 alkenyl, phenyl, tolyl, benzyl, fnrfuryl and furyl respectively. The disulfide compound can promote the growth and the development of plants, promote the formation of flower buds, improve the fruiting rate, protect fruit growth, improve the yield and the quality, kill bacteria, fungi, viruses and nematodes which are harmful to crops in soil, and reduce the using frequency or the dosage of insecticidal and acaricidal agricultural chemicals. 1 to 90 percent of the disulfide compound in percentage by weight and an agriculturally acceptable auxiliary agent are prepared into wettable powder, emulsions, sprayable solutions, concentrated emulsions, aerosols and seed coatings, and are sprayed after being diluted properly, irrigated to roots or splashed to leaf surfaces, stems, fruits or seeds of crops and soil, thus the disulfide compound is a multifunctional green pesticide.