The invention provides an electrode core assembly comprising at least one electrode core, one space ring and one baffle, wherein the electrode core comprises an upper end surface, a lower end surface, two small side surfaces and two big flat side surfaces; the space ring is positioned at the end face of the electrode core, the baffle is positioned at the small side surface of the electrode core, and the space ring and the baffle are fixedly connected. The electrode core assembly can enable the electrode core to be positioned and fixed well so as to prevent the electrode core from shifting in the battery, especially prevent the relative displacement among the small electrode cores in a power battery pack, and reduces circumstances of current collector breakage, septum wrinkle, pole piece fall and the like, and thereby, the service life of the battery is prolonged, and the safety performance of the battery is improved. Moreover, a plurality of electrode cores of the power battery pack are easy to position, combine and assemble, thereby improving the production efficiency. Meanwhile, the invention reduces the mutual friction between the shell of the battery and the electrode core of the arc-shaped side surface, thereby reducing the damage on the electrode core, prolonging the service life of the battery and improving the battery performance.