The invention discloses a preparation method of a catalyst for synthesizing
pyridine base, which comprises the following steps: mixing
bismuth nitrate pentahydrate,
cobalt nitrate hexahydrate and
cadmium nitrate tetrahydrate to prepare a deionized water solution, regulating the pH value to 5 with
nitric acid, dipping an H-ZSM-5
zeolite molecular sieve in a
salt solution, continuously stirring, preserving heat, naturally cooling, washing,
drying, and calcining at high temperature to obtain the catalyst for synthesizing
pyridine base. And uniformly mixing the modified
molecular sieve with the binder of the remaining components, carrying out
spray drying, continuing high-temperature
calcination, filling the formed catalyst into a
fluidized bed reactor, and carrying out activity evaluation by adopting an
aldehyde ammonia condensation process. According to the method, the novel catalyst is prepared by loading
bismuth,
cobalt,
cadmium or other
metal oxides on the ZSM-5 type
zeolite molecular sieve, the reaction is carried out under the
aldehyde ammonia synthesis process condition, the yield of
pyridine in the pyridine base is increased, the
yield ratio of pyridine to 3-methylpyridine can be increased to 20: 1, and the total yield of the pyridine base is kept to be 91.7% or above.