The invention discloses a hydrogeological water quality sampling device and a using method thereof. The device comprises a base, a sampling pipe and an electromagnetic valve, wherein the sampling pipeis connected to the upper end of the base through a clamping groove, a water inlet is formed in one side wall of the sampling pipe, the electromagnetic valve is connected to the water inlet through apipe hoop, and a cover plate is connected to the upper end of the sampling pipe through a clamping groove. The device has the beneficial effects that the structure is novel, and the operation is convenient; as the base, the cover plate, the sampling pipe and the electromagnetic valve are arranged, a large number of sampling specimens can be accommodated; water areas with different depths can be sampled, research data are enriched, the accuracy of research results is guaranteed, a sampling specimen can be protected by arranging a protection box, a floating plate, a box door and an electric push rod, meanwhile, the sampling specimen can be prevented from being polluted by external soil, air and the like in the lifting process, and the safety of the sampling specimen is guaranteed.