The invention discloses a centralized link scheduling method for a multi-channel wireless network. The method comprises the following steps of: 1, numbering links in a network topology based on a wireless network topology consisting of n links, recording the number as 1,2, ..., and n and acquiring a corresponding network conflict graph G through the network topology; 2, acquiring a maximum independent set sequence Iseq of the network conflict graph according to the network conflict graph G in the step 1; and 3, acquiring a maximum group sequence Cseq of the network conflict graph according to the network conflict graph G in the step 1, recording number of elements in the maximum group sequence Cseq as m, wherein each element in the sequence corresponds to a maximum group, and numbering the elements according to a sequence from 1 to m to be recorded as Ci, wherein i is more than and equal to 1 and less than or equal to m. The centralized link scheduling method utilizes space diversity to the greatest degree, maximizes links which are transmitted simultaneously, improves the network capacity and is a conflict-free link scheduling method.