The invention discloses a document data security verification method based on a block chain, which belongs to the technical field of document processing, and is characterized by comprising the following steps: a, a user generates a word document containing a user ID (Identity) by using a national cryptographic algorithm through a word plug-in, and the national cryptographic algorithm comprises an SM2 algorithm and an SM3 algorithm; b, signing the word document, creating user information at a block chain cloud, and generating a CA certificate through a cloud server; c, generating a block through the block chain, binding the CA certificate generated by the cloud server with the user ID, and storing the CA certificate and the user ID in the block; and d, obtaining the certificate of the corresponding user from the block of the block chain according to the user ID of the word document, and completing certificate verification signature. The system has a distributed characteristic, each user can independently sign and verify the electronic document, the precision of a verification result is guaranteed, the electronic document can be written locally, and the operation is more convenient and humanized.