The invention relates to a visible light/radio frequency hybrid cooperative communication method based on wireless energy harvesting and non-orthogonal multiple access, applied to a user cooperative communication system of visible light/radio frequency communication. The system comprises an LED light source and a user group, users in an area closer to the LED light source are near users; and otherusers in the user group are remote users. The method comprises the following steps; (1) within a first stage T time, the near users convert light signals emitted by the LED light source into electricenergy for storage; within a second stage 1-T time, the near users receive the light signals emitted by the LED light source, demodulate the light signals emitted by the LED light source, and demodulate information of the near users and the information of the remote users; and (2) the near users send the demodulated information of the remote users to the remote users through radio frequency signals by using the stored electric energy. In the communication method provided by the invention, the energy consumption problem of the user equipment is also considered, and an energy harvesting moduleis added, thereby being green and environmental friendly.