The invention provides a production method for synthesizing an aqueous
adhesive by using collagen modified by
polyurethane and
epoxy resin. The method includes: firstly, extracting a collagen
hydrolysate from raw materials, such as leftover material of leather manufacturing, bones and the like, which contain the collagen, number-average molecular weight being 10,000 to 30,000; then at 50-80 DEG C,synthesizing an
isocyanate-terminated
polyurethane prepolymer containing a hydrophilic group and mixing the
prepolymer with a certain amount of
epoxy resin, and adding a salt-forming agent so as to form salts with
carboxylic group; finally, adding deionized water, so that during dispersion and
emulsion, the collagen
hydrolysate can be subjected to
grafting reaction with the
polyurethane and epoxyresin, thereby synthesizing the aqueous
adhesive based on the collagen modified by polyurethane and
epoxy resin. In application, a curing agent and filler are not added, or are added to a certain amount, for adhesion of plywoods. With the leftover material of leather manufacturing being a main production
raw material, which is reproducible, the product is free of
formaldehyde, has excellent waterresistance and
adhesion strength, is low in production cost, and can satisfy the use requirement of II-type plywoods. The production method is simple and is easy to control.