The invention relates to environmentally-friendly organic photochromic aqueous
polymer paint and a preparation method thereof. The preparation method comprises the following steps of
emulsion preparation, initiator preparation,
acrylic acid emulsion synthesis and organic photochromic aqueous paint preparation. The characteristic of the environmentally-friendly organic photochromic aqueous
polymer paint is determined by a photochromic compound in the
system, under the excitation action of
ultraviolet ray, a C-O bond of the colorless photochromic compound fractures and causes
isomerization and rearrangement of a molecular structure and
electron configuration, two circular systems connected by C atoms are in a coplane state changed from an orthogonal state and form a large
conjugated system which is a blue color body, and after
ultraviolet ray elimination, a cyclization reaction occurs and the blue color body becomes colorless so that a reversible photochromic
system is formed. The environmentally-friendly organic photochromic aqueous
polymer paint is
environmentally friendly and nontoxic and
photochromism is a reversible
chemical reaction.