2 results about "Electron configuration" patented technology

This invention relates to the field of encryption and anti-counterfeiting technology, specifically to a method for preparing and using an organic Sn(IV)-based metal halide reversible light-emitting conversion triple anti-counterfeiting material, comprising introducing organic ligands into a Sn(IV)X4 lattice and doping with ns 2 This invention uses Sn(IV) with a high oxidation state to replace Pb(II) in order to obtain anti-counterfeiting materials. 4+ The outer electron configuration is 4d 10 5s 0 The absence of unstable 5s orbitals gives Sn(IV)-based metal halides their typically excellent environmental and thermal stability, providing the compounds with a rigid crystal structure and stereochemical inertness. Furthermore, through ns... 2 Type Sb metal ions 3+ Doping strategies are employed to enhance the luminescence efficiency of low-dimensional organotin (IV)-based metal halides. This invention utilizes Sb... 3+ Ion doping methods are used to modulate the optical properties of compounds. Sb 3+ Ions belong to ns 2 Type metal ions and Sn 4+ With similar ionic radii and unique photophysical properties, it solves the problem of low luminous efficiency in existing luminescent materials.

The application relates to the technical field of water treatment, and discloses an iron-based coordination assembly as well as a preparation method and application thereof. The iron-based coordination assembly comprises ferrous ions as central ions, and perfluoroalkyl sulfonic acid and / or perfluoroalkyl carboxylic acid with a perfluorinated carbon chain having 7 or 8 carbon atoms as ligand compounds; and the iron-based coordination assembly forms an active catalytic system in an aqueous solution with a pH value of 4.0-5.0. The iron-based coordination assembly provided by the application retains the active 3d electron configuration of Fe 2+ , and effectively breaks the dense hydration layer around Fe 2+ by using the extremely strong hydrophobic effect of the carbon-fluorine chain of the ligand compound, so that a hydrophobic microenvironment rich in NO2 ‑ is constructed at the active site, thereby greatly optimizing the electron transfer path, and successfully solving the key bottleneck of slow reaction rate and low mass transfer efficiency in the traditional Fe 2+ nitrite reduction technology.