The invention discloses a vehicle accident emergency call system, which comprises a minimum control system, an acceleration sensor, a global position system (GPS) receiver, a Bluetooth audio output adapter, a Bluetooth universal serial bus (USB) adapter, a Bluetooth hands free telephone, a video camera, a wireless data transmission module, a driver information integrated circuit (IC) card and an emergency call center server, wherein Google Earth software is installed in the emergency call center server. According to the system provided by the invention, a Google Earth technology is creatively adopted to acquire intuitive information of an accident location, and two-way interaction between an accident vehicle and an accident emergency call center can be realized, so use efficiency of the emergency call center is improved, and humanization demand is met; the Bluetooth hands free telephone is used as a loudspeaker and a microphone in the system, so a real-time conversation with the accident emergency call center can be realized; and a vehicle-mounted Camera module is arranged in the system, so the accident emergency call center can conveniently observe site conditions in the vehicle.