This invention relates to antistatic biaxially oriented polypropylene (BOPP) combination, using polypropylene as material and including opening agent, smoothness agent, antistatic agent, antioxidant, processing and heat stabilizer, wherein the antistatic agent is glycerin fatty acid ester or two ester, polyethylene glycol ester, amides and/or ethyl amines, the anti-adhesion agent is a series of silicon dioxide inorganic matters or crosslinked polysiloxane particles, the opening agent is the synthesized silicon dioxide or silicates, calcium stearate, the smoothness agent is oleic acid amide, erucic acid amide and/or silicone, and the primary and secondary antioxidants are phosphite stabilizing agent and hindered amine antioxidant. The preparation method includes adding antistatic agent, etc. additives in granulation part, and adding them into PP, mixing, and melting and granulating to obtain the BOPP antistatic resin, or pre-preparing antistatic anti-adhesion smoothness masterbatch by various components. This invention keeps the original performances of BOPP with a lower volume of auxiliaries, and obtain good performances of antistatic property, anti-adhesion, and smoothness.