The invention discloses an electric-energy optimal control method for an intelligent micro-grid with an energy storage device. The method comprises the steps that relevant parameters are initialized; global iteration is started, evaluation network weights and executive network weights are initialized; local iteration is started, an evaluation network and an executive network are trained by utilizing a self-adapting dynamic planning method, and neural network weights are corrected, wherein the evaluation network is used for approximating to an optimal performance index function, and the performance of the current battery control strategy is evaluated by utilizing the evaluation network weights; the executive network is used for approximating to an optimal control strategy and minimizing total cost in the primary global iteration; whether the current local iteration is completed or not is judged, if not, the local iteration is repeated, and if yes, an iteration performance index function and an iteration control law are updated to obtain the optimal solution; whether the current global iteration meets convergence precision or not is judged, if not, the global iteration is repeated, if yes, an optimal battery control strategy is obtained according to the optimal performance index function, and power utilization cost is calculated.