The invention belongs to the technical field of 
wastewater treatment, and in particular relates to a method for pre-treating hard-degradable 
wastewater by a catalyzed iron inner 
electrolysis fluidized bed, which comprises the following specific steps that: a suspended catalyzed iron inner 
electrolysis spherical vector is put into a 
fluidized bed body, wherein the addition amount of the suspended catalyzed iron inner 
electrolysis spherical vector is 10 to 60 percent of the 
active volume of the 
fluidized bed body; 
wastewater to be treated is introduced through a water inlet, and a valve on a 
reflux pipe or an inlet 
pipe is opened and regulated; a hydraulic fluidized 
bed is used as an 
oxygen-deficiency device or a 
hydrolysis device, and a 
reflux amount is determined according to the amount of the 
treated water, the cross sectional area of the 
bed body and the bulk 
specific weight of catalyzed iron fillers; a pneumatic fluidized 
bed is used as an aerobic treatment device, and the 
compressed air amount of the pneumatic fluidized bed meets the requirements of filler 
fluidization on the premise that the dissolved 
oxygen of the wastewater in the device is between 0.5 and 2.5 mg / L; air supply is 6 to 20 times of the amount of the 
treated water; when the pneumatic fluidized bed is used as a 
hydrolysis system, the concentration of the dissolved 
oxygen is less than 0.5 mg / L; the fillers in the fluidized bed body form circulation under the action of an internal guide cylinder and are discharged from a water outlet 
pipe through 
solid-liquid separation in a 
settling region; and a 
sludge discharge pipe is used for discharging residual 
sludge. The method is simple, simple in device structure and strong in 
operability, and can be adapted to the treating scales of different water yields.