The invention discloses a method for strengthening amino benzenes production wastewater SBR biological treatment with synthesized macroporous high-molecular polymer as immobilization microbe. For the drawback of the prior microbe carrier, the invention provides a kind of synthesized high-molecular polymer as immobilization microbe, and applies it to strength amino benzenes production wastewater SBR biological treatment. Compared with prior SBR technique, when microbe carrier used is 2-10% of active volume of the reactor, and the technique condition such as aeration volume, reaction time and temperature equals, with the method, the clearance of amino benzenes materials improves by 35-60% and the concentration of ammonia nitrogen in water outlet decreases by 5-15mg/ L. The invention can be applied for modifying the prior wastewater treatment device, or building new wastewater treatment device, having good economic profit and environmental benefit.