This invention belongs to the field of micro / nano structure
material design and
battery energy storage technology, and relates to a method for preparing a three-dimensional
graphene-COF
interlocking material: First, by controlling the
amination and reduction of
graphene oxide, amine functional groups are precisely constructed on its surface, serving as active sites for heterogeneous
assembly; then, in solution blending, the enhanced multiple intermolecular forces between the amine groups and the COF precursor drive the COF units to undergo oriented adsorption and two-dimensional ordered pre-
assembly on the
graphene surface, forming a molecular-level anchor array; subsequently, through a
solvothermal reaction, interfacial covalent condensation and π-plane-induced epitaxial growth are synergistically achieved, causing the COF layer to crystallize and form a
strongly coupled heterojunction with the deeply reduced and structurally repaired graphene at the
molecular level; finally, after freeze-
drying and shaping, a dual continuous conductive network carrier with a stable heterointerface, three-dimensional
interlocking channels, and an intrinsic built-in
electric field is obtained.