34results about How to "The preparation process is simple and diverse" patented technology

The invention discloses polyimide with low dielectric properties, and a preparation method and an application thereof. The polyimide provided by the invention is prepared through an imidization method by using the raw materials of aromatic diamine comprising triphenylamine and with large side group comprising triphenylethylene / tetraphenylethylene, and various tetra-dianhydrides. The polyimide provided by the invention has ultra-low dielectric constant, relatively low dielectric loss, excellent solubility, relatively high glass transition temperature, relatively high thermal stability, excellent mechanical performances, excellent photo-luminescent performance, and the like. The synthesis method of the polyimide is simple and diverse, and is suitable for industrial productions. The polyimide provided by the invention can be used for preparing low dielectric materials, and can be widely applied in high-tech industry fields such as electronics, microelectronics, information, luminescent materials, aeronautics and astronautics, and specially very large scale integrated circuits.

The invention discloses a flexible lighting polyimide film as well as a preparation method and application thereof. A polyimide material is prepared by carrying out reaction on 1,2,4-triazole aromatic diamine of a strong-sucking electronic structure and various dianhydrides to obtain a polyamide acid liquid, and then carrying out imidization and coating. The flexible lighting polyimide film disclosed by the invention is high in photoluminescence efficiency, high in glass-transition temperature and thermal stability, excellent in mechanical property and the like, and is applicable to preparation of luminous layer materials in a photoluminescence product and a flexible electroluminescence element.

The invention discloses a soluble functional polyimide containing rigid non-planar conjugated structure, and a preparation method and application thereof. The polyimide disclosed by the invention is prepared from aromatic diamine and various tetracid dianhydrides by an imidization method. The polyimide disclosed by the invention is soluble in NMP (N-methylpyrrolidone), DMSO (dimethyl sulfoxide), DMAc (dimethyl acetylamide), DMF (N,N-dimethylformamide), m-Cresol, THF (tetrahydrofuran) and any other conventional organic solvent, and has the advantages of high glass transition temperature, high thermal stability, excellent mechanical properties, photoluminescence and the like. The synthesis method disclosed by the invention has the advantage of simple and multiple techniques, and thus, is suitable for industrial production; and the polyimide disclosed by the invention can be used for preparing photoluminescent materials, and is widely applicable to the fields of high and new technology industries, such as electronics, micro-electronics, information, luminescent material, aerospace and the like.

The invention discloses polyimide with photochromic property and a preparation method and application thereof. The polyimide is characterized in that by adjusting the molecular structure of a photochromic diamine monomer or photochromic dianhydride monomer, different color changes can be obtained; the target monomer can be copolymerized or homogenized with the commercialized diamine or dianhydride, so that the obtained polyimide material has good thermal property and dissolving property. The photochromic polyimide has the advantages that the optical response of different color changes is realized, and the excellent solubility and higher glass transition temperature and thermal stability are realized; the preparation technology is simple and diversified, the condition requirements are low,and the photochromic polyimide is suitable for industrialized production. The polyimide material is spun to obtain a nanometer thin film, and is suitable for preparing photochromic glass films and photo-information storage device materials.

The invention discloses polyimide containing a carbazole structure, a preparation method thereof and application thereof. According to the polyimide, carbazole structure included aromatic diamines high in planarity and various tetracid dihydride are used as raw materials to prepare polyimide powder materials or film through thermal imidization or chemical imidization. The lowest energy state structure of diamine monomers have high planarity and rigidity, the prepared polyimide molecular chain is stacked tightly and has outstanding blocking performance, high glass-transition temperature and heat stability as well as low thermal expansion coefficient. The polyimide preparation method is simple and diversified in process and applicable to industrial production. The polyimide can be widely applied to the field of high and new technology industries such as microelectronics, war industry, aerospace, high-performance packaging and protection and electronic device packaging.

The invention discloses a polyimide nanometer composite with a carbazole structure and a preparation method and application thereof. High-planarity aromatic diamine with the carbazole structure, various types of tetracarboxylic dianhydride and layered nanometer particles are adopted as the raw materials for the composite. In the argon atmosphere, layered nanometer particles are dispersed in strong-polarity non-proton organic solvent, diamine and dianhydride are then added to dispersing liquid, and a polyamide acid composite adhesive solution is obtained after the mixture is stirred and reacts; or, the layered nanometer particles are dispersed, a polyamide acid adhesive solution is prepared from diamine and dianhydride in another container, and then a composite adhesive solution is prepared by mixing the nanometer particle dispersing liquid with the polyamide acid adhesive solution; finally, the polyimide nanometer composite is obtained by dehydrating polyamide acid. Molecule chains of polyimide have good planarity and rigidity; the composite prepared from polyimide and the layered nanometer particles through compositing has excellent thermal stability and isolation performance and can be widely applied to the fields of high-isolation packaging, device packaging and the like.

The invention discloses aromatic hyperbranched polyimide containing an anthracene structure and a preparation method and application of the aromatic hyperbranched polyimide. The hyperbranched polyimide materials are produced through imidization by using triamine containing an anthracene ring structure and multiple tetracid dihydrides as raw materials. The hyperbranched polyimide has high glass transition temperature, thermal stability, good optical properties and good solubility. The synthesis method has a simple and diverse process, and is therefore suitable for industrial production. The hyperbranched polyimide has good application prospects in high temperature-resistant fields, photosensitive materials, optical waveguide materials, gas permeation separation membrane and other material fields.

The invention discloses a high-barrier function polyimide containing a naphthaline structure and a preparation method and application thereof. The polyimide adopts aromatic diamine with the high-planarity naphthaline structure and various kinds of dianhydride as raw materials, and the polyimide is prepared through thermal imidization or chemical imidization. Due to the fact that the lowest energy state structure of a diamine monomer has the high planarity, obtained polyimide molecular chains are compactly stacked and have the excellent barrier performance. The polyimide has the high rigidity and has the high glass-transition temperature, thermal stability and the lower coefficient of thermal expansion. The synthesis method is simple and varied in technology, and therefore the method is applicable to industrial production. The polyimide can be widely applied to the field of high and new technology industries such as high-performance packaging, protection and electronic device packaging.

The invention discloses hyperbranched polyimide containing an anthracene structure and a preparation method and application thereof. The hyperbranched polyimide material is prepared by imidization using a triamine containing an anthracene ring structure and various tetracid dianhydrides as raw materials. The hyperbranched polyimide has high glass-transition temperature and thermal stability, goodoptical performance and good solubility. The synthesis method of the invention is simple and diverse in process and is suitable for industrial production. The hyperbranched polyimide disclosed in theinvention has a good application prospect in the field of high temperature resistance, photosensitivity, optical waveguide, gas permeation separation membranes, etc.

The invention discloses a soluble functional polyimide with a carbazole structure and a preparation method and an application thereof. Polyimide materials use an aromatic diamine with a carbazole structure and a large conjugate structure and various tetracid dianhydrides as raw materials, and polyimide materials are prepared through thermal imidization or chemical imidization. As diamine monomers are provided with large non-planar conjugate structures, so that the polyimide is soluble in conventional organic solvents, and is provided with performances of high glass-transition temperature, thermal stability, photoluminescence, electrochromism, low dielectric constant and the like. The synthesis method is simple in process and diversified, and applicable to industrial production. The polyimide can be widely applied in the new and high technology industry field of electronics, microelectronics, information, luminous materials, aerospace and the like.

The invention discloses polyimide containing a fluorene or fluorenone structure as well as a preparation method and an application of polyimide. The polyimide material takes high-planarity aromatic diamine containing the fluorene or fluorenone structure and various tetracarboxylic dianhydrides as raw materials, and a powder material or film of polyimide is prepared through thermal imidization or chemical imidization. The lowest energy state structure of a diamine monomer has high planarity and higher rigidity, so that the prepared polyimide molecular chains are piled closely, and the preparedpolyimide film has excellent barrier performance, higher glass transition temperature and heat stability and lower thermal expansion coefficient. The synthesis method adopts a simple and diversified process and is thus suitable for industrial production. The polyimide can be widely applied to the field of high-tech industries such as micro-electronics, military industry, aerospace, high-performance packaging and protection, electronic device packaging and the like.

The invention discloses diamine with an antibacterial effect and a preparation method thereof. According to the invention, a two-halogen-atom-substituted xanthone monomer is grafted with an amino-containing group through the Suzuki reaction, or grafted with a nitro-containing group through the Suzuki reaction and then reduced to obtain a diamine monomer containing a xanthone structure. The xanthone structure has high electron density and a good rigid structure; and the planar rigid structure is beneficial for regular stacking of polymer molecular chains and induction of polymer crystallization, and a polymer with tightly stacked molecular chains, small free volume and high barrier property can be prepared. Meanwhile, the diamine disclosed by the invention takes the xanthone structure as acore and has good antibacterial and bacteriostatic effects, and the polymer prepared by taking the diamine as a raw material also has a certain antibacterial property.

The invention discloses a polyimide nano composite containing a fluorene or fluorenone structure and a preparation method and application of the polyimide nano composite. The preparation method includes: adopting aromatic diamine having high planarity and containing a fluorene or fluorenone structure, various tetracid dianhydride and layered nanoparticles as raw materials for reaction to obtain polyimide nano composite gel; imidizing to obtain the polyimide nano composite. The aromatic diamine has high planarity and rigidity, so that polyimide prepared has small free area; seepage path prolonging effect of the layered nanoparticles are combined, so that the polyimide nano composite has excellent blocking performance, thermostability and excellent comprehensive performance. The preparation method is simple and diverse, thereby being suitable for industrial production. The polyimide nano composite can be applied to the field of high and new technology industries like high-performance packaging and protecting and electronic device encapsulating.

The invention discloses aromatic hyperbranched polyimide as well as a preparation method and application thereof. The hyperbranched polyimide material is prepared from aromatic triamine and various types of tetracid dianhydride through imidization. The aromatic hyperbranched polyimide has a high glass-transition temperature and thermal stability, a low thermal expansion coefficient and excellent dissolubility. The synthesis method disclosed by the invention is simple and diverse in process and thus is applicable to industrial production. The hyperbranched polyimide disclosed by the invention has good application prospects in fields such as high-temperature resistance and materials such as gas permeation separation membranes.

The invention discloses a soluble polyimide film with a high refractive index, belonging to the technical field of high molecular materials. The soluble polyimide film mainly comprises polyimide and a sweet clover extract. The polyimide film disclosed by the invention has excellent resolvability and can be dissolved into conventional organic solvents such as N-methylpyrrolidone, dimethyl sulfoxide, N, N-dimethylacetamide, N, N-dimethylformamide, m-cresol, tetrahydrofuran and the like; due to the addition of the sweet clover extract, the refractive index of the material is increased, the light transmittance performance of the material is improved, and the material has relatively high glass transition temperature and thermal stability and excellent mechanical properties; meanwhile, the preparation process is simple and varied and low in condition requirement so as to be suitable for industrial production.

The invention discloses polyimide for an FOLED substrate and a preparation method of the polyimide. The method comprises the following steps: reacting an intermediate containing two halogen atom substituted xanthone with ammonia water to convert halogen atoms into amino groups; and then grafting a nitro-containing group through a Ullmann coupling reaction, then reducing to obtain the diamine monomer containing the xanthone structure, and then polymerizing the prepared diamine monomer with dianhydride to obtain the polyimide containing the xanthone structure. The planar rigid structure and thepolar groups of xanthone are creatively introduced into a polyimide main chain, the planar rigid structure is beneficial to regular stacking of molecular chains and induction of polymer crystallization, and the polar groups can enhance the hydrogen-bond interaction of the molecular chains and promote close stacking of the molecular chains so that polyimide has excellent barrier property, high glass-transition temperature and thermal stability and low thermal expansion coefficient.

The invention discloses a polyimide nanometer composite with a carbazole structure and a preparation method and application thereof. High-planarity aromatic diamine with the carbazole structure, various types of tetracarboxylic dianhydride and layered nanometer particles are adopted as the raw materials for the composite. In the argon atmosphere, layered nanometer particles are dispersed in strong-polarity non-proton organic solvent, diamine and dianhydride are then added to dispersing liquid, and a polyamide acid composite adhesive solution is obtained after the mixture is stirred and reacts; or, the layered nanometer particles are dispersed, a polyamide acid adhesive solution is prepared from diamine and dianhydride in another container, and then a composite adhesive solution is prepared by mixing the nanometer particle dispersing liquid with the polyamide acid adhesive solution; finally, the polyimide nanometer composite is obtained by dehydrating polyamide acid. Molecule chains of polyimide have good planarity and rigidity; the composite prepared from polyimide and the layered nanometer particles through compositing has excellent thermal stability and isolation performance and can be widely applied to the fields of high-isolation packaging, device packaging and the like.

The invention discloses polyimide containing a carbazole structure, a preparation method thereof and application thereof. According to the polyimide, carbazole structure included aromatic diamines high in planarity and various tetracid dihydride are used as raw materials to prepare polyimide powder materials or film through thermal imidization or chemical imidization. The lowest energy state structure of diamine monomers have high planarity and rigidity, the prepared polyimide molecular chain is stacked tightly and has outstanding blocking performance, high glass-transition temperature and heat stability as well as low thermal expansion coefficient. The polyimide preparation method is simple and diversified in process and applicable to industrial production. The polyimide can be widely applied to the field of high and new technology industries such as microelectronics, war industry, aerospace, high-performance packaging and protection and electronic device packaging.

The invention discloses a polyimide nanocomposite of a naphthalene structure and a preparation method and application of the polyimide nanocomposite. According to the composite, aromatic-diamine which has high planarity and of the naphthalene structure, various types of tetracarboxylic dianhydride and layered nanoparticles are adopted as raw materials; in the argon atmosphere, the layered nanoparticles are dispersed in strong-polarity nonprotic organic solvent, then diamine and dianhydride are added to dispersing liquid, stirring and a reaction are conducted, and a polyamide acid composite adhesive solution is obtained; or while the layered nanoparticles are dispersed, the diamine and the dianhydride are placed into another container for preparing polyamide acid, then nanoparticle dispersing liquid and the polyamide acid are mixed, and the composite adhesive solution is obtained; finally, the composite adhesive solution is dehydrated, and the polyimide nanocomposite is obtained. According to the polyimide nanocomposite, polyimide molecular chains of the type contain naphthalene nucleuses which are good in planarity and high in rigidity, the prepared nanocomposite has excellent thermal stability and barrier performance in combination with the enhancement effect of the layered nanoparticles, and the polyimide nanocomposite and the preparation method and application of the polyimide nanocomposite can be widely applied to fields of high-performance packaging, electronic device packaging and the like.

The invention discloses a flexible luminous polyimide film, a preparation method and application thereof. The polyimide material of the present invention adopts aromatic diamine with strong electron-withdrawing structure 1,2,4-triazole and various dianhydrides as raw materials, reacts to obtain polyamic acid solution, and then imidizes and coats prepared. The flexible polyimide film of the present invention not only has high photoluminescent efficiency, but also has high glass transition temperature and thermal stability, excellent mechanical properties, etc., and is suitable for preparing photoluminescent products and flexible electroluminescent devices luminescent layer material.

The invention discloses a hyperbranched polyimide containing a benzothiazole structure and a preparation method and application thereof. The hyperbranched polyimide material is prepared through imidization with triamine containing a benzothiazole structure and various tetracarboxylic dianhydrides as raw materials. The hyperbranched polyimide has high glass transition temperature and heat stability, good optical performance and good solubility. The synthesis method is simple and diverse in technology, thereby being suitable for industrial production. The hyperbranched polyimide has good application prospects in the field of high temperature resistance and the fields of photosensitive materials, optical waveguides and gas permeation separation membranes.

The invention discloses a polyimide with photochromic performance and its preparation method and application. By adjusting the molecular structure of photochromic diamine monomer or photochromic dianhydride monomer, different color changes can be obtained , the target monomer can be copolymerized or homopolymerized with commercial diamine or dianhydride, and the obtained polyimide material has good thermal properties and solubility properties. The photochromic polyimide provided by the present invention has optical responses of different color changes, and has excellent solubility, high glass transition temperature and thermal stability, and the preparation process is simple and diverse, and the condition requirements are low, so Suitable for industrial production. The polyimide material of the invention can obtain a nanoscale thin film through a spin coating method, and is suitable for preparing photochromic glass films and optical information storage device materials.

The invention discloses polyimide with low dielectric properties, and a preparation method and an application thereof. The polyimide provided by the invention is prepared through an imidization method by using the raw materials of aromatic diamine comprising triphenylamine and with large side group comprising triphenylethylene / tetraphenylethylene, and various tetra-dianhydrides. The polyimide provided by the invention has ultra-low dielectric constant, relatively low dielectric loss, excellent solubility, relatively high glass transition temperature, relatively high thermal stability, excellent mechanical performances, excellent photo-luminescent performance, and the like. The synthesis method of the polyimide is simple and diverse, and is suitable for industrial productions. The polyimide provided by the invention can be used for preparing low dielectric materials, and can be widely applied in high-tech industry fields such as electronics, microelectronics, information, luminescent materials, aeronautics and astronautics, and specially very large scale integrated circuits.

The invention discloses polyimide of a fluorene-containing or fluorenone-containing structure as well as a preparation method and application of the polyimide. The polyimide material uses aromatic diamine of a high-planarity fluorene-containing or fluorenone-containing structure and various dianhydrides as raw materials; powder materials or films of the polyimide are prepared through hot imidization or chemical imidization. The lowest energy state structure of diamine monomers has high planarity and higher rigidity; the prepared polyimide molecular chain piling is tight, so that the prepared polyimide film has excellent blocking performance, higher vitrification conversion temperature, high thermal stability and lower heat expansion coefficient. The synthesis method has the advantage that the process is simple and diverse, so that the method is applicable to industrial production. The polyimide disclosed by the invention can be widely applied to the field of high and new technology industries such as micro-electronics, military industries, aerospace, high-performance package and protection and electronic device packaging.

The invention discloses naphthalene structure-containing high heat-resistant hyperbranched polyimide as well as a preparation method and application thereof. A hyperbranched polyimide material is prepared through imidization by taking triamine containing a naphthalene ring structure and various tetracid dianhydride as raw materials. The hyperbranched polyimide has higher glass-transition temperature, higher thermal stability, lower thermal expansion coefficient and good solubleness. A synthetic method disclosed by the invention is simple in technology and is diversified, so that the syntheticmethod is suitable for industrial production. The hyperbranched polyimide disclosed by the invention has a better application prospect in the field of high temperature resistance and material fields of photosensitive materials, optical waveguide materials, gas permeation and separation films and the like.

The invention discloses a hyperbranched polyimide with a phenanthrene ring-containing structure, a preparation method and an application thereof. Such a hyperbranched polyimide material is prepared through the imidization of raw materials, including triamine with the phenanthrene ring-containing structure and various tetracid dihydrides. Such a hyperbranched polyimide has higher glass-transition temperature and heat stability, lower thermal expansivity and excellent solubleness. The synthetic method disclosed by the invention has simple and various processes, so that the method is suitable forindustrial production. The hyperbranched polyimide disclosed by the invention has an excellent application prospect in the field of high temperature resistance and the field of materials, such as photosensitive, optical waveguide and gas permeation separating membranes.