The application discloses an
electrolyte crystallization simulation method and device based on
Gibbs free energy minimization, equipment and medium, relates to
chemical engineering separation
simulation calculation technical field, and the method is to obtain the
material flow, component composition and other working condition parameters of the crystallizer feed
stream, and the
temperature and pressure operating conditions of the target
system, and the
solid phase component information of the
electrolyte to be precipitated; based on the principle of
Gibbs free energy minimization, the total
Gibbs free energy objective function is constructed, the
solid-
liquid phase equilibrium problem is converted into a nonlinear
programming problem with constraints by applying equality and non-negative constraints; the
solid-
liquid phase equilibrium result is obtained by using the
interior point method, and finally, the
crystallization solid
phase fraction is determined, and the
liquid phase composition, solid phase type and
crystallization amount are output. The application does not need to preset the solid phase
precipitation sequence, is suitable for complex systems with multiple salt coexistence and multiple solid phase competitive
precipitation, significantly improves the solving stability and calculation accuracy, and can be directly integrated into
chemical process simulation software, thereby providing reliable bottom calculation support for crystallization
process design.