The invention discloses a method for constructing a law model of plasma generated by propellant powder, belonging to the field of plasma, the method comprises the following steps: S1, under the hypothesis of an inner trajectory and in a high-pressure state, a firing pin impacts the bottom of a hearth, primer is ignited, main charge is ignited through the primer, the main charge is combusted to generate high-temperature and high-pressure fuel gas, the fuel gas is used for doing work and pushing the projectile to move, and finally the projectile is launched out., S2, constant volume state analysis, S3, combustion process assumption, S4, plasma rule model construction and S5, model verification. The construction method disclosed by the invention is more scientific and reasonable; the physical process of propellant powder combustion is analyzed, the internal ballistic theory, the combustion theory, the plasma theory and the like are combined, a mathematical model of the plasma generation law of propellant powder under the high-pressure state is finally established, the result of numerical simulation is compared with the test result, and the correctness and feasibility of the model are determined.