The present invention relates to aluminum electrolysis, and is especially inert ceramet anode. The ceramet material has structure of at least two layers and is rod shaped, plate shaped or cup shaped. The ceramic phase is spinelle type composite oxide; and the metal phase is made of Cu, Ni, Co, Fe, Ag, Pt, Au and other metal or their binary or multiple-element alloy. The composite material with gradient function has excellent comprehensive performance under electrolysis, and the anode of the composite material needs no frequent replacement. Using the composite material of the present invention can alter the electrolytic bath structure, raise production efficiency, lower aluminum ingot producing cost, improve environment, and reduce power consumption.