The present invention relates to a guide plate and instruction plate using photo luminescent porcelain enamel that includes an improved guide plate and instruction plate implemented in such a manner that aluminum, steel, copper, alloy plate, etc., after removing of anti-rust oil (lubricant), are preprocessed for an easier adherence, and a primary coat enamel and a necessary coat enamel are processed, and a ground surface is processed with non-photo luminescent porcelain enamel; and character, number, symbol, graphic, image, pattern, etc. of the guide plate and instruction plate are molded with photo porcelain enamel.