The invention discloses a valve-group-controlling urea spraying system and a control method thereof. The urea spraying system comprises a urea tank, a urea spray nozzle, a cooling water pipeline, a compressed air pipeline, a urea pipeline, a blow-off pipeline, a purging pipeline and a valve group spraying unit. The valve group spraying unit comprises a controller, a cooling water electromagnetic valve, a first air electromagnetic valve, a second air electromagnetic valve, a pressure regulating device, a purging electromagnetic valve, a spraying electromagnetic valve, a pressure sensor, a blow-off electromagnetic valve and a temperature sensor. Motive power is provided for the whole system through compressed air, metering is carried out through all the electromagnetic valves, feedback control over the opening degrees of the electromagnetic valves is performed through the temperature sensor and the pressure sensor, the urea spraying process is finished with low cost and high accuracy; and by means of the special purging pipeline and the special purging electromagnetic valve, purging can be performed on an upper section and a rear section of the urea pipeline, and thus the whole ureapipeline is free of residual urea after a car stops.