A novel high-gain double-input DC-DC converter comprises an input unit, a first boosting unit, a second boosting unit and a load unit, wherein the input unit comprises three inductors L1, L3 and L4, four capacitors C3, C5, C7 and C8, three power switches S1, S2 and S3 and four diodes D1, D2, D3 and D4; the first boosting unit comprises an inductor L2, a capacitor C4 and a diode D5, and the second boosting unit comprises an inductor L5, a capacitor C6 and a diode D6. Compared with an existing scheme, the converter can remarkably reduce the number of times of electric energy conversion among the micro power source, the storage battery and the load, improves the electric energy conversion efficiency, has the advantages of being wide in input and output voltage adjusting range, low in switching device voltage stress and the like, and can achieve N-path boost expansion.