The invention belongs to the field of organic electroluminescence, and particularly relates to an iridium metal compound with a deuterium-fluorine synergistic effect and a photoelectric device containing the iridium metal compound. The structure of the iridium metal compound is shown as a structural formula I, R1 to R17 are partially or completely deuterated substituents, and at least one of R1, R2, R3, R6, R7, R8, R10, R11, R12, R14, R15 and R16 is a fluorine atom. The iridium metal compound has better thermal stability and lower evaporation temperature, and the energy transmission efficiency between a main body material and an iridium metal complex is remarkably improved, specifically, when the iridium metal compound is used as a light-emitting layer material of an organic light-emitting device, the current efficiency of the light-emitting device is improved, the driving voltage is reduced, the service life is obviously prolonged, and a good commercial prospect is achieved.