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Organic small molecular photoelectric functional material adopting 3-benzoylpyridine as receptor unit as well as preparation method and application thereof

The invention discloses an organic small molecular photoelectric functional material adopting 3-benzoylpyridine as a receptor unit, which mainly depends on hydrogen-bond interaction of nitrogen in benzoylpyridine, can effectively avoid the deficiency of low radiation rate caused by large torsion angle, thereby improving the horizontal molecular orientation, and realizing the structure simplification of devices and performance of the devices and prolonging the service life. By controlling the type and size of a donor connecting unit, the intrinsic characteristics of the material such as a molecular weight, a conjugated length, charge transfer and the like can be effectively adjusted. The invention also discloses a preparation method and application of the organic small molecular photoelectric functional material. The organic small molecular photoelectric functional material adopting 3-benzoylpyridine as the receptor unit has the advantages that the radiation rate coefficient is high, the quantum efficiency is high, the current carrier transport performance is high, the color is adjustable when being used as a luminescent layer of an organic electroluminescent device, high efficiencyand stability can be realized, the service life is long, and the like.
Owner:SOUTH CHINA UNIV OF TECH

Organic compound and application thereof, and organic electroluminescent device comprising organic compound

The invention relates to an organic compound which is characterized in that the organic compound has a structure as shown in a formula (1), in the formula (1), X1 is selected from one of CR1R2, NR3, O, S or SiR4R5, and when R3 exists, R3 is optionally connected with a ring D to form a fused ring structure; the ring E, the ring D and the ring A are independently selected from one of substituted or unsubstituted C6-C30 aromatic rings and substituted or unsubstituted C3-C30 heteroaromatic rings respectively; ar is a structure as shown in a formula (a); z1 is selected from C or Si; z2 is selected from one of CR6R7, NR8, O, S and SiR9R10, and a is 0 or 1; y1-Y4 are respectively and independently selected from C, CR13 or N, and Y5-Y8 are respectively and independently selected from CR13 or N; r1 to R13 are independently selected from one of hydrogen, a substituted or unsubstituted C1-C10 chain alkyl group, a substituted or unsubstituted C3-C10 cycloalkyl group, a substituted or unsubstituted C1-C10 alkoxy group, a substituted or unsubstituted C1-C10 silyl group, a substituted or unsubstituted C6-C30 aryl group and a substituted or unsubstituted C3-C30 heteroaryl group, and R13 is optionally independently connected with an aromatic ring or an aromatic heterocyclic ring to form a ring.
Owner:BEIJING ETERNAL MATERIAL TECH
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