The invention provides a photoelectric winding, which is used for a transformer from 0.1 kilovolt to 1100 kilovolt work voltage, a reactor, a cassette mechanism and an electric generator of the inductor, and a stator, a rotor, and the like, of an electric motor. The guide line of the photoelectric winding is photo copper wire or photo aluminum wire. The photoelectric winding transmits electrical energy, and can sense or transmit correlative information such as temperature or electric current or pressure, etc. The photo copper wire or the photo aluminum wire is manufactured by extruding opticalfiber or optical fiber bundle packed in electricity conducting metallic copper or aluminum billet. The photoelectric winding can sense and transmit correlative work condition information such as temperature, electric current, pressure, and the like, when the photoelectric winding works, therefore, the photoelectric winding leads power equipment to have a self-check alarming function, provides fundamental guarantee for the good operation of equipment and accident avoidance, is intellectualized electrical power telecommunication equipment, and has epoch-making meaning.