Disclosed is a refining and selection method of the mixed metal particles in the high voltage electrostatic field which relates to the mixed metal refining and selection technical field. The invention discloses a refining and selection method, firstly, two or more than two kinds of mixed metal particles with the grain sizes of 0.1mm-3mm are selected, the high voltage direct current power supply of a small-sized high voltage purifying machine is switched on, applied voltage value UA can be selected according to parameters such as densities, radii and radii of the columnar earthing electrodes of the mixed particles, and then the mixture is sent into a feed slot, and refining and selection can be fulfilled under the function of the high voltage electrostatic field. The invention is characterized by simple structure, little energy consumption, no loss during refining, high grade of metal particle refining. The novel method for mixed metal refining is suitable for refining and selection with two or more than two kinds of mixed metals that have certain density contrasts and are particles or can be crashed to particles. The invention is mainly used in metal material recovery field such as disused car and electronic waste recovery.