The invention relates to a method for preparing a tourmaline/titanium oxide composite sol and its purposes. The mass percentage of raw materials and feeds is listed: titanate with 5-15%, anhydrous alcohol with 60-90%, organic acid with 3-13%, inorganic acid with 2-15%, deionized water with 0.5-1.5%, tourmaline with 0.001-3%, tombarthite with 0.0004-0.0008%, the total is 100%. The said titanate is one of the kinds such as methyl titanate, ethyl titanate, butyl titanate, titanic chloride and titanoxy sulfate. The said organic acid is one of the kinds such as acetic acid, oxalic acid, formic acid and monosulfonic acid. The said inorganic acid is one of the kinds such as concentrated sulfuric acid, concentrated nitric acid and concentrated chlorhydric acid. The said tourmaline is one or more of the kinds such as iron-tourmaline, elbaite and dravite. The said tombarthite is one of the kinds such as lanthanum, europium nitrate, erbium nitrate, cerous nitrate and neodymium nitrate. The invention also provides the method for preparation of the said sol and its main purposes.