The invention belongs to but is not limited to the technical field of electrochemical containers, and particularly relates to a double-
hybrid electrochemical
capacitor and a preparation method thereof, the double-
hybrid electrochemical
capacitor comprises a
hybrid positive
electrode and a hybrid negative
electrode, and the hybrid positive
electrode and the hybrid negative electrode simultaneously comprise two
energy storage mechanism active materials of double-electric-layer electrostatic
energy storage and Faraday quasi-
capacitance energy storage. An active material of the double-electrode-layer electrostatic energy storage mechanism is open-pore
activated carbon, the port aperture of the open-pore
activated carbon is smaller than or equal to 0.2 nm, and the pore web size is 1-1.5 nm. In the manufacturing process of the
capacitor, the electrochemical principle is utilized, the positive electrode and the negative electrode are subjected to electrochemical hybridization design at the same time, on one hand, the upper limit of the working
voltage of the electrochemical capacitor is increased to 4.4 V from 2.7 V through introduction of a Faraday quasi-capacitor energy storage mechanism active material at the positive electrode end, and therefore
effective energy storage of the capacitor is greatly enhanced; the volume
energy density is greatly improved; and on the other hand, high-
power output characteristic matching of the
system is simultaneously introduced and maintained at the positive electrode end and the negative electrode end through a double-electric-layer electrostatic energy storage mechanism active material.