The invention discloses a shield tunneling construction method for an n-shaped underground diaphragm wall. The shield tunneling construction method comprises the following steps of step I, formulating a construction process flow; step II, performing the specific construction process: firstly, measuring and setting out; secondly, manufacturing a guide wall; thirdly, preparing and adjusting slurry; fourthly, trenching the underground diaphragm wall and performing bottom-clearing replacement; fifthly, manufacturing and hanging a GFRP (Glass Fiber Reinforced Plastic) reinforcement cage; sixthly, manufacturing and setting a bamboo reinforcement cage; seventhly, grouting underwater concrete; eighthly, constructing joints; ninthly, topping a joint pipe. The shield tunneling construction method disclosed by the invention has the beneficial effects that a tunnel door is not needed to be manually chiseled, so the construction period is greatly shortened; a soil body on the outer side of an envelope structure is not needed to be reinforced, so the construction cost of engineering is reduced; the envelope structure directly plays roles of retaining soil and stopping water at the shield tunneling stage, and the safety of the shield tunneling is greatly guaranteed.