The invention belongs to the technical field of secondary batteries and preparation thereof, and relates to a charging method of a
sodium ion battery, the
sodium ion battery and application. The technical problems that in the prior art, a
sodium ion battery is low in
capacitance during low-temperature charging, and sodium
precipitation of a negative
electrode is serious are solved. The invention provides a charging method of a sodium-ion battery, which comprises the following steps: acquiring the constant volume capacity C0 of the sodium-ion battery at normal temperature, charging the battery to 0.5 time of the constant volume capacity C0, and acquiring the charging
tail end
voltage V1; standing the battery at a target low temperature in an empty
electricity state, charging the battery to 0.5 times of C0, and obtaining a charging
tail end
voltage V2 of the battery;
delta V is calculated to be equal to V2-V1, and when
delta V is larger than or equal to X, the battery is charged to be fully charged by adopting a sectional charging method; and when
delta V is less than X, the battery is firstly charged to 0.7 time C0, and then the battery is fully charged by adopting a sectional charging method. According to the invention, the low-temperature charging performance is optimized, the sodium-ion battery is charged to a fully charged state at a low temperature, the phenomenon of sodium
precipitation of a negative
electrode in a low-temperature charging process is avoided, and the safety of the battery is improved.