This invention provides a method and
system for the supermicrowave
digestion and determination of
thallium in ores. Based on X-
ray fluorescence spectroscopy, the matrix insolubility index is calculated to establish the
digestion decision variables. Redundant points are eliminated using Sobol sequences combined with Thiessen polygons, and a non-uniform experimental design is constructed to obtain training data. On this basis, a
hybrid response surface model is constructed, and
kernel partial least squares regression is applied to fit the main trend,
Gaussian process regression is used to process the residuals, and the interference index is introduced as a
hyperparameter. The Grey Wolf optimization
algorithm, incorporating Lévy flight, is used to optimize the ore while ensuring low residual organic carbon and maximizing the
recovery rate. The obtained optimal parameters are used for supermicrowave
digestion of the ore, and the
thallium content is determined by ICP-MS, achieving efficient and accurate detection.