The invention relates to a process and a special device for refining and removing alum continuously for TiCL4, which solves the problems that the TiCL4 has production cost, needs frequent washing, replacement and supplementation of copper wires, can not implement continuous operation, has high labor intensity and cause environmental pollution. The process is as follows: mineral oil and rough TiCL4 is added into a circulating system according to a proportion of between 1.2 to 1000 and 1.6 to 1000, and VOCL3 in the mineral oil and the TiCL4 contacts adequately and react to generate a high boil point matter; materials are forced to be circulated and heated by a circulating pump, and the heating temperature is between 137 and 145 DEG C; the mineral oil and the TiCL4 are continuously added into the circulating system according to the output requirement, so as to realize the continuous production; a semi-finished product of the TiCL4 is obtained after distillation, and the high boil point matter and other high boil point impurities in the distillation are removed. The special device for finely producing and removing alum continuously for the TiCL4 consists of a rough tatinium overhead tank, the circulating pump, a heat exchanger, a mixer, a distillation kettle, an alum slurry tank, a packing tower, a condenser, a semi-finished tank, a mineral oil grove and a metering pump.