The invention relates to a two-phase
electrolyte and an electrochemical device, the two-phase
electrolyte comprises an
electrolyte salt, water and an
organic solvent, the difference value of the Hildbrand
solubility parameter of the water and the Hildbrand
solubility parameter of the
organic solvent is 13.5-15.3, and the relative
dielectric constant of the
organic solvent is 5-80. The water phase-organic phase in the double-phase electrolyte provided by the invention can realize spontaneous phase separation, and the double-phase electrolyte is a stable water phase-organic phase double-phase electrolyte, so that the problems of negative
electrode hydrogen evolution
corrosion, dendritic
crystal growth and the like can be solved, and the
ion transmission efficiency is improved; the battery using the two-phase electrolyte shows better long-term cycle life and high capacity
retention rate.