The invention belongs to the field of sewage treatment and particularly relates to a novel clean environment-friendly coagulant and a production method thereof. Given the problems of slow coagulation, bad viscous dissipation effect, water pollution and the like of existing coagulant, the invention provides a novel clean environment-friendly coagulant and a production method thereof. The novel clean environment-friendly coagulant consists of the following components in percentage by weight: 10-15% of organic modified bentonite, 15-20% of modified chitosan, 10-12% of modified starch, 3-5% of sodium carbonate, 1-2% of baking soda and the balance of water. The production method comprises the following steps: sequentially adding the baking soda, sodium carbonate, modified starch, modified chitosan and organic modified bentonite into the water; and adjusting the pH to obtain the novel clean environment-friendly coagulant. In the invention, the coagulation speed of the coagulant is high, the viscous dissipation effect is good, and water pollution is avoided; and moreover, the production raw materials are easily available, the operation is easy, and the production cost is saved.