The invention discloses a 
ceramic diaphragm with a multilayer 
composite structure and a battery using the 
ceramic diaphragm. The 
ceramic diaphragm with the multi-layer 
composite structure comprises an organic microporous base material, a 
ceramic coating layer, a three-dimensional high-temperature-resistant layer and a 
polymer layer; the 
ceramic coating layer is attached to one surface or two surfaces of the organic microporous base material, the thickness of the 
ceramic coating layer is 0.1-50 microns, the ceramic 
coating layer comprises inorganic 
powder and a binder, and the particle size of the inorganic 
powder is 5nm-50 microns; holes are distributed in the organic microporous base material; the three-dimensional high-temperature-resistant layer continuously coats the surface of the ceramic 
coating layer and the inner walls of the holes and comprises a high-temperature-resistant 
polymer and a curing cross-linking agent, and the high-temperature-resistant 
polymer comprises phenolic resin, 
urea resin, 
polyimide or 
epoxy resin; the thickness of the polymer layer is 5nm-10mu m, and the polymer layer coats on the surface of the three-dimensional high-temperature-resistant layer. The ceramic diaphragm has good adhesion with positive and negative electrodes, and the battery with the ceramic diaphragm has the advantages of high safety, long service life and the like.