The invention relates to the technical field of concrete and preparation thereof, in particular to a self-insulation lightweight concrete wall which is prepared from, by weight, 25-45 parts of coal ash, 15-35 parts of cement, 15-30 parts of fine sands, 5-12 parts of diatomite, 3-12 parts of composite porous fibers, 15-48 parts of light aggregates, 3-8 parts of waste rubber particles, 1-3 parts offirst foaming agents, 0.5-1.5 parts of water reducing agents and 0-5 parts of other auxiliaries. The composite porous fibers are prepared from, by weight, 10-30 parts of first polymer powder, 18-56 parts of second polymer powder, 0.6-10 parts of second foaming agents, 1-6 parts of carbonate, 10-30 parts of chain extenders and 5-20 parts of oxidized graphene. The self-insulation lightweight concrete wall has the advantages of light weight, high strength and good weather resistance.