The invention discloses a high-entropy oxide negative electrode energy storage material containing bismuth, tin and antimony as well as a preparation method and application of the high-entropy oxide negative electrode energy storage material. The material is a multi-element high-entropy oxide material with five or more elements, wherein the multi-element high-entropy oxide material is composed of one or more of bismuth, tin and antimony and nickel, cobalt, manganese, copper, chromium, iron, indium, germanium, magnesium, aluminum, zinc, molybdenum, tungsten, vanadium or titanium. Preparing a uniform composite precursor from the element metal salts through one of physical ball milling, freeze drying, solvothermal, sol-gel or coprecipitation methods; and placing the obtained precursor in an annealing furnace, and annealing in the air at 300-700 DEG C for 0.5-48 hours to obtain the product. Due to the entropy stabilization effect and the phase stabilization effect, as the negative electrode material of the potassium, sodium and lithium ion battery, the internal stress generated by the volume change of metal oxide negative electrode particles in the charging and discharging process is relieved, the expansion of cracks in the particles is inhibited, the pulverization and component segregation of the negative electrode particles are avoided, the integrity of the electrode is kept, the structure is stable, and the cycle performance is good.