The invention provides a method for forming self-alignment duplex pattern. The method comprises the following steps: providing a material layer to be etched, forming a sacrificial photoresist layer on the material layer to be etched, curing the sacrificial photoresist layer, forming a first mask pattern on the side wall surface of the sacrificial photoresist layer, and removing the sacrificial photoresist layer. As the sacrificial photoresist layer is cured, the hardness of the sacrificial photoresist layer is increased, and during the process of forming the first mask pattern, the sacrificial photoresist layer does not deform under the stress generated by the first mask material layer, so that the side wall of the sacrificial photoresist layer is still perpendicular to the surface of the material layer to be etched, and finally, the side wall of the etched pattern which is formed by etching the material layer to be etched has a better profile.