The invention discloses a lightweight concrete block for environment-friendly construction and a preparation method of the lightweight concrete block. The invention belongs to the technical field of buildings. According to the invention, an innovative mode of throwing the spontaneous gas inner vibrating ball can be realized, based on the magnetic repulsion effect, the magnetic particles are autonomously and uniformly distributed in the slurry, then, the gas generation action is triggered under the heating action, the built-in gas-forming powder begins to be heated and decomposed to release gas, the natural gas is released into the slurry along a gas-forming outer hopper on the natural gas-forming inner vibrating ball, fine and uniform air holes are formed, the concrete building block has aporous structure, the traditional gas generating material is replaced, meanwhile, when the spontaneous gas inner vibrating ball releases gas, high frequency vibration is formed in the slurry so thatthe fluidity and uniformity of the slurry are improved, thus indirectly improving the strength of the block. According to the self-aerated concrete block, the self-aerated inner vibration ball is arranged in the slurry, high-frequency vibration is formed in the slurry, the fluidity and uniformity of the slurry are improved, the strength of the block is indirectly improved, the self-aerated inner vibration ball and the block can form a tight whole, the strength of the block is further improved, a large pore channel is reinforced, and a block forming process is greatly improved.