The present invention provides a method of manufacturing a
layered structure and an apparatus for manufacturing a
layered structure where the
layered structure comprises a
solid electrolyte layer, a positive
electrode active material layer, and a negative
electrode active material layer, which together constitute an all-
solid-state battery, enables the
interfacial resistance to be lowered, enables the interfacial strength to be increased, enables an improved
yield rate, and enables a low manufacturing cost.The layered structure that has concavities and convexities formed on the surface is manufactured by the method comprising steps of:forming a green sheet S111, where the green sheet for a
solid electrolyte layer 11 is formed; forming concavities and convexities S112, where (1) the green sheet for a solid
electrolyte layer 11 and (2) the sheet member 50 that is made from material that is caused to disappear when heated, and that has concavities and convexities, are formed in one piece, and the concavities and convexities are formed on the surface of the green sheet for a solid electrolyte layer 11; heating S113, where the sheet member 50 is caused to disappear by heating the green sheet for a solid electrolyte layer 11 and the sheet member 50 that are formed in one piece, and where the green sheet for a solid electrolyte layer 11 is sintered.