The preparation method of the high-permeability high-efficiency
sulfuric acid catalyst comprises the following steps: adding
vanadium pentoxide powder into a
potassium sulfate supersaturated solution, dispersing, and adding
potassium hydroxide and
sodium sulfite until
potassium hydroxide and
sodium sulfite are dissolved; the preparation method comprises the following steps: slowly adding dilute sulphuric acid at the constant temperature of 60-80 DEG C, adjusting the acid-base property to be neutral, adding
polyethylene glycol (6000),
sodium benzenesulfonate, soluble
starch and organic
silicon, stirring at the constant temperature for 15-30 minutes, adding macroporous
silicon dioxide
powder, stirring for 10 minutes, adding dilute sulphuric acid, and stirring at the constant temperature for 20-30 minutes to obtain a colloidal catalytic activity intermediate; performing equal-
mass separation and reunion dispersion on disc-shaped diatomite and straight-chain diatomite to obtain a mixed carrier; and mechanically stirring and mixing the colloidal catalytic activity intermediate, the mixed carrier and the
organic matter additive until the catalytic activity substance is fully dispersed in a diatomite skeleton and pore channels, molding to obtain a catalyst wet blank,
drying and
roasting to obtain the product. The catalyst is good in air permeability, high in catalytic activity and high in
thermal stability.