The invention relates to a flexible conductive composite fabric, and preparation and application thereof. The flexible conductive composite fabric comprises a conductive 
composite film (1), a base fabric (2) and an 
adhesive (3), wherein the base fabric (2) is adhered on the upper and lower surfaces of the conductive 
composite film through the 
adhesive (3); and two ends of the conductive 
composite film (1) are respectively adhered with an 
electrode. The flexible conductive composite fabric is prepared through the following steps: impregnating a 
carbon nanotube thin film in a 
graphene suspension, then taking the 
carbon nanotube thin 
film out of the 
graphene suspension, and carrying out 
drying in the air so as to obtain a 
carbon nanotube / 
graphene composite film; allowing a 
polyaniline nanowire array to grow in situ on the surface of the carbon 
nanotube / graphene composite film so as to obtain a carbon 
nanotube / graphene / 
polyaniline composite film; and respectively adhering an 
electrode at two ends of the composite film, 
coating the base fabric on the upper and lower surfaces of the composite film through the 
adhesive, and carrying out curing so as to obtain the flexible conductive composite fabric. The prepared conductive fabric provided by the invention has good 
conductivity, can reach 103 S / m to 105 S / m, can bear a certain degree of bending and 
compressive deformation, and is extensively applied in the fields of intelligent 
textile structures and intelligent materials.