The invention discloses a near-field dynamic modeling method for a composite mass diffusion problem. The method comprises the following steps of 1, building an entity model; 2, cutting the entity model, determining layering and mixing region positions of materials in the model, and giving corresponding material attributes to the regions; 3, dividing the entity model into unit grids; 4, setting concentration boundary conditions of the entity model; 5, on the basis of mass diffusion near-field dynamic constitutive relation, integrating model parameters, determining a calculation method for concentration changes of a diffusing substance in a composite in the entity model, and calculating operation parameters of all units in the entity model; 6, performing submission calculation. The modelingmethod is high in precision and good in grid adaptability, all the parameters in the model are preprocessed, the operation complexity can be greatly lowered, and an algorithm is greatly optimized; themodeling method and the operation process are large in adaptability and applicable to many problems.