The invention discloses a steel galvanized layer surface water treatment agent. The steel galvanized layer surface water treatment agent consists of the following components in percentage by mass: 38-45% of water metal silicon acrylic resin, 5-10% of tetramethylsilane, 2-4% of ammonium metavanadate, 1-3% of sodium molybdate, 5-7% of coal tar, 8-10% of 98% concentrated sulfuric acid, 2-3% of 35% formalin, 1-2% of wetting agent, 1-2% of defoaming agent, 1-2% of potassium sorbate, and 23-25% of de-ionized water. The steel galvanized layer surface water treatment agent is excellent in material selection, adopts a scientific processing method to solve the problem of surface corrosion of a traditional steel galvanized layer, converts the surface rust to a useful passivation film, prevents the steel surface corrosion, is high in self-healing performance and excellent in construction performance, brakes at normal temperature or low temperature, is fast in drying, uses the de-ionized water as a dispersion medium, contains no chromic acid or dichromate, methylbenzene, ethylbenzene and dimethylbenzene, is low in VOC, is free of combustion, explosion and pollution, has the heavy metal content lower than the national compulsory standard, is free of pungent smell, is free of poison and harm to human bodies, and is prominent in environment benefit, economic benefit and social benefit.