47results about How to "Good anti-HIC performance" patented technology

The invention discloses micro-alloying seamless pipeline steel and process for preparation. According to weight percentage, the range of the chemical components of the invention includes that C holds 0.08% to 0.20%, Si is equal to or less than 0.04%, Mn takes 0.60% to 1. 50%, S is equal to or less than 0.015%, P is equal to or less than 0.025%, Al is equal to or less than 0.04%, Ti is equal to or less than 0.04%, H is equal to or less than 2.5*10-4%, O is equal to or less than 25*10-4%, the rest is Fe and unavoidable foreign matters. The process for preparation comprises technique steps, including smelting, refining, continuous casting, hot rolling and slow cooling. Round steel with the size of phi 70 to 150 millimeters can be produced by the process for preparation. The seamless pipeline steel of the invention has perfect anti-sulphide stress corrosion (SSC resistance) capability and anti-HIC property. The pipeline steel which can substitute for welding pipe can be utilized in the filed of oil pipeline and the like, and the invention increases the reliability of material and adaptability of variety, in particular being adaptable for the low submarine temperature and corrosion-resistant environment and for manufacture of thick-walled tubes.

The X65 pipeline steel for use in acid condition consists of C 0.02-0.05 wt%, Mn 1.20-1.50 wt%, Si 0.10-0.50 wt%, S not more than 0.0020 wt%, P 0.004-0.012 wt%, Nb 0.05-0.07 wt%, Ti 0.005-0.025 wt%, Mo 0.050-0.195 wt%, Cu not more than 0.35 wt%, Ni not more than 0.35 wt%, N not more than 0.0080 wt%, Ca 0.0015-0.0045 wt% and Ca/S not less than 2.0 except Fe. Its making process includes the following steps: smelting in a converter or an electric furnace; secondary steel making including LF desulfurizing + RH vacuum deairing and Ca treatment; continuous casting; rolling with initial rolling termination temperature of 940-1020 deg.c and finish rolling termination temperature of 780-840 deg.c; and winding at 500-580 deg.c. The X65 pipeline steel has low manufacture cost, high HIC resistance, high dynamic tear resistance and high impact toughness.

The invention discloses super-thick X70 pipeline steel and a manufacturing method thereof, wherein the pipeline steel is 30-32mm thick, and the pipeline steel comprises the following chemical ingredients in percentage by mass: 0.03-0.06% of C, 0.1-0.30% of Si, 1.30-1.60% of Mn, less than or equal to 0.010% of P, less than or equal to 0.0050% of S, 0.030-0.050% of Nb, 0.008-0.020% of Ti, 0.10-0.30% of Ni, 0.l0-0.30% of Cr, 0.10-0.30% of Cu and the balance being Fe and inevitable impurity elements. smelting raw materials are sequentially subjected to KR molten iron pretreatment, converter smelting, LF refining and RH vacuum degassing to obtain molten steel which is relatively high in purity, and then the pipeline steel, which is high in thickness, high in strength, narrow in strength interval, excellent in low-temperature toughness, and excellent in both low-temperature resistant aging performance and HIC resistance, is obtained through a controlled rolling and controlled cooling process.

The invention relates to non-copper and nickel acid resistant pipeline steel X52MS. The non-copper and nickel acid resistant pipeline steel X52MS comprises the following components in percentage by weight: 0.02-0.06 wt% of C, 0.05-0.35 wt% of Si, 1.0-1.4 wt% of Mn, P not greater than 0.018 wt%, S not greater than 0.003 wt%, 0.10-0.50 wt% of Cr, 0.05-0.10 wt% of Ti, 0.005-0.10 wt% of Nb, 0-0.05 wt% of V, and the balance of Fe and inevitable trace impurities. The invention further provides a preparation method of a hot-rolled plate coil of the non-copper and nickel acid resistant pipeline steel X52MS. Part of all Cr is used for replacing original Ni/Cu elements, so that the material cost is largely reduced under the precondition of guaranteeing the material HIC resistance.

The invention discloses an economic HIC-resistant X90 pipeline steel plate. The steel plate comprises the following chemical components by mass percent: 0.02 to 0.06% of C, 1.7 to 1.90% of Mn, 0.15 to 0.35% of Si, 0.0005% of less of S, 0.010% of less of P, 0.04 to 0.07% of Nb, 0.008 to 0.03% of Ti, 0.10% or less of V, 0.06% of less of Al, 0.010% or less of N, 0.006% or less of O, 0.20% of less of Mo, 0.20% or less of Cu, 0.20% or less of Ni, 0.20% or less of Cr and 0.0005 to 0.0015% of Ca, and the balance being Fe and unavoidable impurity elements, wherein the ratio of the content of Ca to the content of S is 1.0 to 2.0. According to the economic HIC-resistant X90 pipeline steel plate, the improved technology of refining, continuous casting, high temperature reheating and TMCP is adopted according to the behavioral rule of hydrogen in structures, so that the steel has an excellent structure resisting HIC and has excellent low-temperature toughness.

The invention discloses a pipeline steel plate for HIC (hydrogen induced cracking)-resistant X80 elbow pipes. A component design principle is characterized in that a proper amount of C (carbon) and Mn (manganese) is added, a trace amount of microalloying elements of Nb (niobium), V (vanadium), Ti (titanium) and the like is added, a small amount of Mo (molybdenum), Cu (copper), Ni (nickel) and the like is added, and a particular TMCP (thermo mechanical control process) technology is combined, so as to finally ensure the mechanical properties, especially HIC-resistant property at high carbon equivalent. The manufacturing process comprises the following steps of preparing materials according to a proportional ratio; sending into a converter or an electric furnace to smelt; refining outside the converter or the electric furnace; continuously casting; reheating a plate blank; performing TMCP technology and stack cooling after water cooling; straightening. The pipeline steel plate for the X80 elbow pipe has the advantages that the particular TMCP comprises two-phase rolling and intermediate blank cooling, so that the problem of HIC-resistant property at high carbon equivalent is solved; and the HIC-resistant property of pipeline steel plate for X80 elbow pipes is excellent.

The invention provides an X52 seamless pipeline tube having HIC resistance and a manufacturing method thereof. The X52 seamless pipeline tube comprises the following components in percentage by weight: 0.08-0.16% of C, 0.2-0.4% of Si, 1.0-1.6% of Mn, 0.01-0.04% of Ti, 0.03-0.08% of V, 0.20-0.30% of Cu, 0.15-0.25% of Ni, less than or equal to 0.015% of P, less than or equal to 0.010% of S and the balance of iron and unavoidable impurities. The manufacturing method comprises the following steps: heating a tube billet obtained by hot rolling to 1200 DEG C-1300 DEG C by virtue of an annular furnace, carrying out continuous rolling method by virtue of an MPM, carrying out quenching and tempering heat treatment and carrying out strip temperature straightening at a temperature not less than 400 DEG C. By screening and matching alloying elements and carrying out heat treatment method of quenching and tempering, the HIC resistance of the tube is improved, the grain structure is uniform, good impact toughness is achieved and the manufacturing method is easily implemented.

The invention relates to hydrogen induced cracking (HIC)-resistant heat resistant steel in an iron element system and a preparation process thereof. The steel comprises the following components in percentage by weight: 0.1 to 0.15 percent of C, 0.2 to 0.5 percent of Si, 0.3 to 0.6 percent of Mn, 2.0 to 2.5 percent of Cr, 0.9 to 1.1 percent of Mo, less than or equal to 0.003 percent of S, less than or equal to 0.010 percent of P and the balance of iron and impurities. The preparation process comprises a heating process, a hot rolling process and a heat treatment process sequentially, wherein the heat treatment process comprises a normalizing process and a tempering process. The steel has a high comprehensive mechanical property, a high low-temperature impact property, high HIC resistance and relatively low tempering tendering sensitivity; and the preparation process is simple, easy to operate, low in cost, high in yield and wide in thickness specification ranges, and a small number of alloys with a few varieties are added.

The invention discloses an X80 pipeline steel plate for conveying coal-derived natural gas and a manufacturing method thereof. Steel comprises 0.019%-0.059% of C, 0.15%-0.45% of Si, 0.55%-1.85% of Mn,0-0.50% of Cu, 0-0.50% of Cr, 0-0.50% of Ni, 0.05%-0.35% of Mo, 0.03%-0.12% of Nb, 0.01%-0.04% of V, 0.008%-0.024% of Ti, 0.01%-0.04% of Al, 0-0.010% of P, 0-0.005% of S, and the balance Fe and unavoidable impurities, and S+P+O+N+H<=0.015%. The superheat degree of molten steel is 15-25 DEG C, the soft reduction rate is 2%-5%, and the drawing speed is 0.8-2.0 m/min. Two-section heating is adopted,rough rolling starting temperature is larger than or equal to 1000 DEG C, fine rolling starting temperature is 800-900 DEG C, fine rolling finish temperature is 750-850 DEG C, cooling starting temperature is 710-770 DEG C, cooling finish temperature is 460-600 DEG C, and the cooling speed is 5-20 DEG C/s. the steel plate has good strength, toughness and HIC resistance.

The invention provides a VC nanoparticle-strengthened X90 steel plate for a plastic pipe, and a manufacturing method thereof. The steel plate comprises the following components in percentage by weight: 0.06%-0.12% of C, 0.10%-0.30% of Si, 0.60%-1.40% of Mn, 0.07%-0.15% of V, 0.001%-0.004% of N, 0.01%-0.04% of Ti, 0.025%-0.045% of Al, not greater than 0.010% of P, not greater than 0.005% of S, 0.10%-0.30% of Cu, 0.10%-0.30% of Mo, 0.10%-0.30% of Cr, 0.10%-0.30% of Ni and the balance Fe and inevitable impurity elements. The manufacturing method comprises the following steps: material preparation, converter or electric furnace smelting, external refining, casting, plate blank reheating, controlled rolling and controlled cooling. The steel plate produced by the manufacturing method meets the various mechanical property requirements of the X90 steel plate for the plastic pipe, and is especially high in low-temperature toughness and anti-HIC property.

The invention discloses a solid gas protection welding wire used for welding a crude oil carrier cargo oil tank boat deck. The mass percentage ratios of the chemical elements are as follows: 0.02-0.10% of C, 0.30-0.60% of Si, 0.80-1.00% of Mn, 0.02-0.10% of Ti, 0-0.50% of Mo, 0.20-0.50% of Cr, 0.01-0.10% of Al, 0.10-0.80% of Cu, 0.10-0.80% of Ni, and the balance of Fe and other unavoidable impurities. The tensile strength of the solid gas protection welding wire used for welding the crude oil carrier cargo oil tank boat deck provided by the invention is greater than 440 MPa, and the impact work of a weld metal at 20 DEG C below zero is greater than 47 J, so that the solid gas protection welding wire has good corrosion resistance. Besides, the solid gas protection welding wire used for welding the crude oil carrier cargo oil tank boat deck and a mother board for welding have the consistent corrosion resistance and pitting resistance.

The invention discloses a method for producing an ultra-low-temperature high-core-impact-value acid-resistant container steel by using a casting blank. The method comprises the following steps of determining the steelmaking components; carrying out a heating process; carrying out a tapping and rolling process; and carrying out a heat treatment process. According to the method, the ultra-low-temperature high-core-impact-value acid-resistant container steel is produced through the design of being low in carbon and small in chromium alloy component amount in combination with the reasonable rolling control and cooling control, quenching and tempering and heat treatment processes, so that the mechanical property reaches the technical standard requirements, and the acid resistance meets the requirements of NACE-TM2084-2016, the actual level of the mechanical property reaches the following standards that the yield strength is greater than or equal to 340 MPa, the tensile strength is greater than or equal to 480 MPa, the elongation is greater than or equal to 35%, the transverse Akv at the core of a steel plate and at 60 DEG C below zero is greater than or equal to 240 J, the HIC resistance reaches the standards that CLR is equal to 0%, CTR is equal to 0%, and the CSR is equal to 0%, and therefore, the problems of unstable low-temperature impact property, poor HIC resistance, unstableweldability and the like of the production of the ultra-low-temperature high-core-impact-value by using a casting blank in the prior art are solved.

The invention relates to a production method of acid-resistant pipeline steel. The steel comprises the following chemical components in percentage by mass: 0.02-0.04%of C, 0.15-0.35% of Si, 1.10-1.25%of Mn, less than or equal to 0.010% of P, less than or equal to 0.0015% of S, 0.020-0.045% of Alt, 0.015-0.045% of Nb, 0.010-0.020% of Ti, 0.08-0.15% of Mo, 0.08-0.15% of Ni, 0.08-0.20% of Cu, less than or equal to 0.0005% of B, 0.12-0.14% of Pcm and the balance Fe and inevitable impurities. By adopting an online quenching and tempering process, a steel plate with thickness of 8-26.4 mm * 65MS isproduced, and the steel plate has high strength and ultra-strong low-temperature toughness, wherein the yield strength is 480-530 MPa, the tensile strength is 570-630 MPa, the elongation A50 is 35%-55%, the yield ratio is smaller than or equal to 0.88, the impact at 60 DEG C below zero is 300-400 J, and the drop hammer at 40 DEG C below zero is 85%-100%.

The invention provides an Nbc nano-particle reinforced steel plate for X90 plastic pipes and a manufacturing method of the steel plate. The steel plate comprises, by weight, 0.06-0.12% of C, 0.10-0.30% of Si, 0.60-1.40% of Mn, 0.07-0.15% of Nb, 0.01-0.004% of N, 0.01-0.04% of Ti, 0.025-0.045% of Al, not greater than 0.010% of P, not greater than 0.005% of S, 0.10-0.30% of Cu, 0.10-0.30% of MO, 010-0.30% of Cr, 0.10-0.30% of Ni and the balance being Fe and other inevitable impurity elements. The manufacturing method includes the steps of preparing of materials, smelting in converter or electric furnace, external refining, casting, reheating of plates, controlled rolling and controlled cooling. The steel plate produced by the method has good plastic deformation capacity, and can guarantee safety of oil and gas transmission pipelines laid in zones with complex geological conditions.

The invention discloses a production method for X80 grade pipeline steel resistant to hydrogen-induced cracking (HIC), and belongs to the technical field of metal materials. The production method forthe X80 grade pipeline steel resistant to HIC includes the technical processes of converter smelting, vacuum Si-Ca processing, casting into ingot blanks, ingot blank heating, rough rolling, precisionrolling, cooling and curling. The components of the ingot blanks include, by mass percentage, 0.02-0.04% of C, 0.20-0.23% of Si, 0.60-0.80% of Mn, 0.20-0.30% of Cu, 0.30-0.45% of Cr, 0.20-0.25% of Mo,0.03-0.05% of Nb, 0.02-0.03% of V, 0.01-0.02% of Ti, 0.005% or less of P, 0.002% or less of S, and the balance Fe and unavoidable impurities. The ingot blank heating temperature, rough rolling temperature, precision rolling temperature and cooling mode are controlled, and the X80 grade pipeline steel with low cost and good HIC resistance is prepared.

The invention relates to the technical field of petroleum pipes, in particular to a corrosion resistant low-chromium oil bushing used in an environment in which CO2 and H2S coexist. Aiming at overcoming the problem of relatively high cost of pipes in solving the problem that the oil bushing is liable to be corroded with increasing coexistence environments of CO2 and H2S in the prior art. The technical proposal provided by the invention is that the oil bushing comprises the following compositions: C: 0.18-0.24%, Si: 0.25-0.50%, Mn: 0.45-0.55%, P: 0.01-0.015%, S: 0.003-0.005%, Cr: 2.95-3.10%, Mo: 0.40-0.75%, Cu: 0.10-0.25%, Ni: 0.009-0.05%, Al: 0.015-0.055%, Ti: 0.010-0.035%, B: 0.0018-0.0024%, Nb: 0.03-0.06% and V: 0.05-0.10%; controlled compositions (wt%) are as follows: ratio of As, Sn, Sb, N, Ca/S is 1.5 and the balance is Fe. Compared with the prior art, the invention has the advantages of superior effect and on increase in cost.

The invention discloses submarine X70-grade pipeline steel resistant to hydrogen sulfide corrosion. The submarine X70-grade pipeline steel resistant to the hydrogen sulfide corrosion comprises the following components of, in percentage by weight, 0.02%-0.03% of C, 0.23%-0.26% of Si, 1.10%-1.20% of Mn, 0.10%-0.15% of Ni, 0.25%-0.30% of Cr, 0.12%-0.16% of Mo, 0.004%-0.006% of Mg, 0.04%-0.07% of Nb,0.03%-0.05% of V, 0.01%-0.02% of Ti, not more than 0.005% of P, not more than 0.002% of S and the balance Fe and inevitable impurities. A production method of the submarine X70-grade pipeline steel resistant to the hydrogen sulfide corrosion comprises the following steps that 1) smelting is carried out in a converter, Mg treatment is carried out in conventional vacuum, and casting and blank forming are carried out; 2) a cast blank is heated, and the heating temperature of the cast blank is controlled to be 1220-1250 DEG C; 3) the starting temperature of rough rolling is 1030-1080 DEG C, the ending temperature of rough rolling is 970-990 DEG C, and the total reduction rate is 65%-75%; (4) the starting temperature of finish rolling is 870-910 DEG C, the ending temperature of finish rolling is 840-870 DEG C, the cumulative reduction rate of finish rolling is not lower than 65%, and a steel plate with the thickness of 12 mm is formed through seven passes of rolling; and (5) laminar coolingis carried out, and the steel plate is cooled to 450-510 DEG C at the cooling speed of 40-60 DEG C/s, and curled for later use. Compared with the prior art, the submarine X70-grade pipeline steel resistant to the hydrogen sulfide corrosion has the advantages of being high in strength, high in toughness and high in hydrogen sulfide corrosion resistance.