The invention discloses a burning-free brick and a preparation method thereof. The burning-free brick comprises 30-45 parts of domestic waste incineration fly ash, 10-15 parts of alkaline substances, 5-10 parts of industrial waste residue, 30-45 parts of water glass and Solvent 0-25 part; Wherein, described industrial waste slag is two or three kinds in waste calcium carbonate, casting waste sand, iron ore tailings slag; Waste slag, water glass and solvent are excited and stirred by alkali to make brick slurry, and then the slurry is discharged into the mold, and after shaking, pressing and curing, it is made into non-burning brick. The process of the invention is simple and the cost is low, and the unburned bricks produced by the invention also have good environmental friendliness and strength, can be applied as building bricks, have strong practicability, and effectively solve the problem of difficult disposal of fly ash from domestic waste incineration .